期刊
ORGANIC LETTERS
卷 19, 期 16, 页码 4311-4314出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01975
关键词
-
资金
- University of Michigan
- Bristol Myers Squibb Graduate Research Fellowship
Intermolecular alkene difunctionalization reactions between terminal alkenes bearing a pendant aryl or alkenyl triflate electrophile and exogenous alcohol or phenol nucleophiles are described. These transformations afford substituted indanyl or alkylidenecyclopentyl ethers in high yield with excellent diastereoselectivity. The transformations proceed through intermolecular capture of an intermediate [pd(II)-alkene]+[OTf](-) complex by the alcohol or phenol nucleophile.
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