期刊
ORGANIC LETTERS
卷 19, 期 15, 页码 4034-4037出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01786
关键词
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资金
- UNSW Canberra postgraduate research student scholarship scheme
Two new glycoluril diethers have been prepared, bearing strained cyclobutene and cyclobutane rings at the fused junction of the two imidazolidinone rings. The wide angle of the concave face of the cyclobutano derivative enabled the synthesis of c-ydobutanocucurbit[5-8]uril, the largest member being the most significant achievement. A limited binding affinity study compared the new substituted family to classical cucurbit[5-8]uril. Surprisingly lower affinities were found, except for cyclobutanocucurbit[6]uril, which was 3.3-fold higher.
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