期刊
ORGANIC ELECTRONICS
卷 51, 期 -, 页码 362-403出版社
ELSEVIER
DOI: 10.1016/j.orgel.2017.09.038
关键词
P3AT; P3HT; Crystalline structure; Electronic device
Poly (3-alkylthiophenes) (P3ATs) particularly poly (3-hexylthiophene) (P3HT) have vigorous tendency to crystallize into the ordered morphologies, thereby reflect the efficient electrical and optical characteristics. Here, the remarkable crystalline structures of P3ATs comprising single crystals, nanofibers, nano/microwires, nanoribbons, micelles, nanowhiskers, thin films, spherulites, etc. are thoroughly reviewed. In each category, the principle aspects like preparation methodologies (e.g., self-seeding, shearing, electrospinning, self-organization, epitaxial solidification, etc.), micro/nanostructures, orientation and optical properties are meticulously brought into consideration. Applications of the ordered P3AT structures in solar cells, organic field-effect transistors, and sensors as well as the theoretical studies are also highlighted. Furthermore, the polymorphism, sol-gel, nanoparticles, liquid crystalline morphology, and two-dimensional sheets are reviewed.
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