期刊
ORGANIC ELECTRONICS
卷 50, 期 -, 页码 255-263出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2017.07.055
关键词
Transparent electrode; Silver nanowires; Reduced graphene oxide; Solution-processing; Flexible polymer solar cells
资金
- National Basic Research Program of China [2014CB643504]
- National Natural Science Foundation of China [51325303, 21334006, 51611530705]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12030200]
It is reported a kind of solution-processible transparent conductive film consisting of reduced graphene oxide (rGO) nanosheets and silver nanowires (AgNWs). The sandwiched structure of rGO/AgNWs/rGO is readily deposited via layer-by-layer blade-coating on the rigid glass or flexible PET substrate at mild annealing temperature. The rGO nanosheets sandwiching the AgNWs networks not only induce close contact of the AgNWs networks as a clipper to improve the conductivity, but also link the discrete AgNWs as a connector to improve the uniformity of the film conductivity. The transparent rGO/AgNWs/rGO film exhibits sheet resistance as low as 14.29 U/, with transmittance over 90% at 550 nm. Moreover, the rGO/AgNWs/rGO composite film shows good ambient stability due to the rGO coverage and the existing charge interaction between AgNWs and rGO. Polymer solar cells are fabricated on the transparent rGO/AgNWs/rGO-coated glass or flexible PET substrates and they exhibit comparable photovoltaic perfromance to the control devices fabricated on the commercial ITO substrate. More importantly, the PSCs based on the rGO/AgNWs/rGO/PET substrate show more excellent flexibility than that of the device based on the ITO/PET substrate. (C) 2017 Elsevier B. V. All rights reserved.
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