期刊
ORGANIC ELECTRONICS
卷 43, 期 -, 页码 229-234出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2017.01.038
关键词
Perovskite solar cell; Stability; Thin film
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [24246009, 25107719, 15H03552]
- Advanced Low Carbon Technology Research and Development Program from the Japan Science and Technology Agency (JST-ALCA) [J121052556]
- Grants-in-Aid for Scientific Research [25107719, 15H03552] Funding Source: KAKEN
We demonstrate the degradation mechanism of CH3NH3PbI3 perovskite solar cells (PSCs) and their recovery effects by introduction of CH3NH3I layers. After degradation by exposure to air under a 1-sun condition for 18 h, the absorption of the CH3NH3PbI3 perovskite between 530 and 800 nm decreases, and thereby the energy band gap increases. X-ray diffraction (XRD) patterns indicate that moisture with sunlight corrodes the CH3NH3PbI3 perovskite into PbI2, which generates cracklike voids on the surface of illumination-degraded CH3NH3PbI3 perovskite thin films. As a result, the PSC photovoltaic performance is degraded and the power conversion efficiency (PCE) is reduced from 16.8 to 0.7%. However, the PCE is recovered to 7.6% by spin-coating a CH3NH3I layer into the illumination-degraded CH3NH3PbI3 perovskite thin films. The recovery of the absorption between 530 and 800 nm and the CH3NH3PbI3-perovskitc-assigned peaks in the XRD patterns verifies that the illumination-induced PbI2 is recombined with spin coated CH3NH3I and that the CH3NH3PbI3 perovskite structure is recrystallized. (C) 2017 Elsevier B.V. All rights reserved.
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