期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 8, 页码 1810-1820出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02827f
关键词
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资金
- JSPS KAKENHI [16K05769]
- Sumitomo Foundation
- Grants-in-Aid for Scientific Research [16K05769] Funding Source: KAKEN
Various 1-substituted-imidazo[1,5-a]pyridin-3-ylidenes were prepared and characterized. The fundamental character and the effects of substituents on the imidazo[1,5-a]pyridine backbone on the electronic character of carbenes were evaluated using rhodium complexes and selenium adducts. C-13 NMR chemical shifts of carbene carbons in imidazo[1,5-a]pyridin-3-ylidene and H-1 and C-13 NMR spectra of olefin moieties trans to the carbene in Rh(nhc)(cod) Cl complexes shifted relatively downfield compared to those for the corresponding complexes bearing conventional N-heterocyclic carbenes (NHCs). The IR peak of the trans-carbonyl moiety of Rh(nhc)(CO)(2)Cl complexes appeared at a higher wavenumber than for conventional NHCs. These observations suggest that imidazo[1,5-a]pyridin-3-ylidene ligands have strong pi-accepting character. Rh(nhc)(CO)(2)Cl complexes were further characterized by X-ray diffraction analyses. To obtain further insight into the electronic character of imidazo[1,5-a]pyridin-3-ylidenes, selenoureas were prepared. We found that a combination of both the Se-77 NMR chemical shift and (1)J(C-Se) coupling constant of C-Se bonds are appropriate for a rigorous evaluation of the electronic characters of imidazo[1,5-a]pyridin-3-ylidenes, but did not correspond to those for conventional NHCs. DFT calculations for imidazo[1,5-a]pyridin-3-ylidenes revealed that a hybrid accepting orbital comprised of a vacant pi-orbital of carbene and a pi* orbital of the pyridine ring newly occurred to result in significantly increased pi-accepting character. Finally, the strong pi-accepting character of the ligand was demonstrated by the Rh-catalyzed polymerization of phenylacetylene.
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