期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 43, 页码 9057-9060出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02366a
关键词
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资金
- National Natural Science Foundation of China [U1404209, 21202078]
- Aid Project for the Leading Young Teachers in Henan Provincial Institutions of Higher Education of China [2015GGJS-113, 206GGJS-118]
A photoredox-catalyzed direct difluoromethylation of alkynoates has been developed. A well-designed photoredox system induces a single-step, regioselective installation of CF2H onto alkynes. Difluoromethyl sulfone was used as an easy to handle CF2H radical source to afford the desired 3-difluoromethylated coumarins in moderate to good yields via a radical-triggered tandem difluoro-methylation/5-exo cyclization/ester migration process.
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