期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 41, 页码 8770-8779出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02038d
关键词
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资金
- key research & development program in Jiangsu [BE2015683]
- introduction program of leading scientific and technological entrepreneurship in Nanjing [2013B14007]
- innovative research project of graduate student in Jiangsu [KYLX16_1170]
An efficient and applicable I-2-catalyzed intramolecular dehydrogenative C-O/C-N coupling reaction via activating the C-H bond adjacent to the N atom has been developed to provide dozens of substituted benzoxazinones (31 examples) and quinazolinones (5 examples) in good to excellent yields (up to 98%). This one-pot methodology has significant advantages, including a metal-free process, broad substrate scope, high atom economy, and simple operation. This strategy goes through an iminium intermediate followed by nucleophilic attack to provide the desired products.
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