期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 21, 页码 4506-4516出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00908a
关键词
-
资金
- European Research Council [ERC-CoG 614182-IonPairsAtCatalysis]
This Review summarises the recent progress made in the organocatalytic synthesis of atropisomeric compounds. Methodologies based on dynamic kinetic resolution and direct access to BINOL-like biaryls are described. A particular emphasis is given to reaction mechanisms and to the development of strategies to obtain stable products by increasing the barrier to atropisomer interconversion during the reaction.
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