期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 18, 页码 3863-3868出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00599g
关键词
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资金
- National Natural Science Foundation of China [21662029, 21262027]
- Young Scientists Foundation of Shihezi University [RCZX201546, 2015ZRKXJQ05]
- Excellent Young Teachers Plan of Bingtuan
A novel organocatalytic olefinic carbon-sulfur bond forming reaction was developed. Under the catalysis of 10 mol% stable N-heterocyclic carbene, thiols undergo direct nucleophilic substitution reaction with gem-difluoroalkenes to produce alpha-fluorovinyl thioethers in high yields with excellent Z-selectivity. In this process, bases are not necessary.
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