期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 14, 页码 2906-2909出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00535k
关键词
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资金
- Russian Scientific Fund [14-50-00069]
- Russian Science Foundation [14-50-00069] Funding Source: Russian Science Foundation
Imidazoline-fused [1,4] oxazepines (prepared in two simple steps from methyl 2-hydroxyaroates, ethylene diamine and bis- electrophilic aromatics) undergo a facile, good-yielding hydrolytic imidazoline ring expansion (HIRE) upon N-alkylation and treatment with aqueous K2CO3. The resulting arene-fused ten-membered lactams significantly add to the contemporary arsenal of smallmolecule scaffolds where medium-sized ring systems are severely underrepresented.
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