期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 2, 页码 316-319出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02546c
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资金
- Pierre Potier foundation for the chemistry of natural products
We herein introduce a straightforward synthetic route to cysteine-containing cyclic peptides based on the intramolecular native chemical ligation of in situ generated thioesters. Key precursors are N-Hnb-Cys crypto-thioesters, easily synthesized by Fmoc-based SPPS. The strategy is applied to a representative range of naturally occurring cyclic disulfide-rich peptide sequences.
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