期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 3, 页码 708-716出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02398c
关键词
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资金
- Department of Science and Technology, New Delhi [SB/S1/OC-42/2013]
- Board of Research in Nuclear Sciences (BRNS), Government of India (Basic Sciences) [2013/37C/59/BRNS/2443]
- Council of Scientific and Industrial Research (CSIR), New Delhi
A collective synthesis of a gamma-butyrolactone class of paraconic acids such as (+)-methylenolactocin, (+)-phaseolinic acid, (+)-nephrosteranic acid, (+)-nephrosterinic acid, (+)-rocellaric acid and (+)-protolichesterinic acid is described. The strategy adopted is protecting-group-free based on efficient Pd-catalyzed Suzuki-Miyaura coupling and Ru-catalyzed Sharpless oxidation to construct the core beta-CO2H-gamma-butyrolactone unit to accomplish the synthesis of various paraconic acids.
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