期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 6, 页码 1407-1417出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02420c
关键词
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资金
- National Nature Science Foundation of China [21302156]
- NSFC-Shandong Joint Fund for Marine Science Research Centers [U1406402]
- Scientific and Technological Innovation Project - Qingdao National Laboratory for Marine Science and Technology [2015ASKJ02-06]
- Ocean University of China [OUC 201562031]
An asymmetric aldol-desymmetrization sequence was developed which provided highly efficient access to important bicyclic oxygen-containing scaffolds with multiple chiral centers and one is a quaternary stereogenic center containing a free hydroxy group. Moreover, starting from racemic precursors, the final products were obtained as two separable diastereomers by flash chromatography. Several other heterocycles could also be easily generated with this strategy.
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