期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 15, 期 1, 页码 51-55出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01812b
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资金
- University of Colorado at Boulder
Cyclic phosphonium anhydrides generated from bis-phosphine oxides and trifluoromethanesulfonic anhydride are shown as general coupling reagents in a dehydrative glycosylation reaction of C1-hemiacetals. This reaction protocol is characterized by a broad substrate scope and high yields, including reactions of O-, C-, N-, and S-based nucleophiles with furanose, pyranose, and deoxysugar donors.
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