期刊
ENERGY
卷 79, 期 -, 页码 363-370出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2014.11.022
关键词
Adsorption isotherms; Adsorption kinetics; Ethanol; Metal organic framework
资金
- Japan Science and Technology Agency (JST), Core Research for Evolutional Science and Technology (CREST)
This paper presents experimental and theoretical investigations of adsorption characteristics of ethanol onto metal organic framework namely MIL-101Cr. Adsorption isotherms and kinetics of the studied pair have been measured gravimetrically using a magnetic suspension adsorption measurement unit and volumetrically employing a Quantachrome Autosorb iQ MP machine. The present experiments have been conducted within relative pressures between 0.1 and 0.9 and adsorption temperatures ranging from 30 to 70 degrees C, which are suitable for adsorption cooling applications. Adsorption isotherm data exhibit that 1 kg of MIL-101Cr can adsorb as high as 1.1 kg of ethanol at adsorption temperature of 30 degrees C, and the Toth equation has been used to fit the experimentally measured data. As of the experimentally measured adsorption uptake rate data, the Fickian diffusion model is found to be suitable. These data are essential for designing a new generation of adsorption chiller. (C) 2014 Elsevier Ltd. All rights reserved.
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