期刊
GREEN CHEMISTRY
卷 20, 期 22, 页码 5209-5214出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8gc02782j
关键词
-
资金
- Institute for Basic Science [IBS-R010-G1]
An efficient, transition metal-free trifluoromethylative pyridylation of unactivated alkenes was achieved by visible-light-induced photoredox catalysis employing CF3SO2Na and a pyridinium salt in the presence of eosin Y as a photoredox catalyst. The overall process is thought to occur by the selective addition of an electrophilic CF3 radical to the alkene substrate to provide an alkyl radical intermediate, which subsequently engages in an addition to the pyridinium salt. This three-component photocatalytic strategy circumvents traditional multistep procedures and readily affords synthetically and biologically important trifluoromethyl- and pyridyl-containing frameworks.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据