期刊
METALS, MINERALS, AND SOCIETY
卷 21, 期 -, 页码 89-114出版社
SOC ECONOMIC GEOLOGISTS, INC
DOI: 10.5382/SP.21.06
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资金
- U.S. National Science Foundation [152439, EAR 1250239]
- MSI grant Millennium Nucleus for Metal Tracing along Subduction [NC130065]
- FONDECYT [1140780]
- FONDAP [15090013]
- Society of Economic Geologists
Iron oxide copper-gold (IOCG) and Kiruna-type iron oxide-apatite (IOA) deposits are commonly spatially and temporally associated with one another, and with coeval magmatism. Here, we use trace clement concentrations in magnetite and pyrite, Fe and O stable isotope abundances of magnetite and hematite, H isotopes of magnetite and actinolite, and Re-Os systematics of magnetite from the Los Colorados Kiruna-type 10A deposit in the Chilean iron belt to develop a new genetic model that explains IOCC and IOA deposits as a continuum produced by a combination of igneous and magmatic-hydrothermal processes. The concentrations of [Al + Mn] and [Ti + V] are highest in magnetite cores and decrease systematically from core to rim, consistent with growth of magnetite cores from a silicate melt, and rims from a cooling magmatic-hydrothermal fluid. Almost all bulk delta O-18 values in magnetite are within the range of 0 to 5 parts per thousand, and bulk delta Fe-56 for magnetite are within the range 0 to 0.8 parts per thousand of Fe isotopes, both of which indicate a magmatic source for O and Fe. The values of (delta O-18 and delta D for actinolite, which is paragenetically equivalent to magnetite, are, respectively, 6.46 +/- 0.56 and -59.3 +/- 1.7 parts per thousand, indicative of a mantle source. Pyrite grains consistently yield Co/Ni ratios that exceed unity, and imply precipitation of pyrite from an ore fluid evolved from an intermediate to mafic magma. The calculated initial Os-187/Os-18(8) ratio (Os-i) for magnetite from Los Colorados is 1.2, overlapping Os-i values for Chilean porphyry-Cu deposits, and consistent with an origin from juvenile magma. Together, the data are consistent with a geologic model wherein (1) magnetite microlites crystallize as a near-liquidus phase from an intermediate to mafic silicate melt; (2) magnetite microlites serve as nucleation sites for fluid bubbles and promote volatile saturation of the melt; (3) the volatile phase coalesces and encapsulates magnetite microlites to form a magnetite-fluid suspension; (4) the suspension scavenges Fe, Cu, Au, S, Cl, P, and rare earth elements (REE) from the melt; (5) the suspension ascends from the host magma during regional extension; (6) as the suspension ascends, originally igneous magnetite microlites grow larger by sourcing Fe from the cooling magmatic-hydrothermal fluid; (7) in deep-seated crustal faults, magnetite crystals are deposited to form a Kiruna-type IOA deposit due to decompression of the magnetite-fluid suspension; and (8) the further ascending fluid transports Fe, Cu, Au, and S to shallower levels or lateral distal zones of the system where hematite, magnetite, and sulfides precipitate to form IOCG deposits. The model explains the globally observed temporal and spatial relationship between magmatism and IOA and IOCG deposits, and provides a valuable conceptual framework to define exploration strategies.
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