期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 91, 页码 12860-12862出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07479h
关键词
-
资金
- China Scholarship Council
An expedient route to the pentacyclic core of the tryptoquivaline alkaloids and the total synthesis of natural product (+)-3-(4-oxoquinazolin-3-yl)spiro[1H-indole-3,5-oxolane]-2,2-dione (1) have been achieved. The route is enabled by a key, highly stereoselective, aldol reaction catalysed by a Ag(i) and cinchona-derived aminophosphine ligand system, forming a highly substituted oxazoline ring, and setting the C1 spirocyclic stereocentre for downstream manipulation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据