期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 91, 页码 12832-12835出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07032f
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Catalytic regioselective generation of an allyl-Cu complex through Cu-B(pin) (pin = pinacolato) addition to 1,3-dienes followed by reaction with an electrophilic cyanation reagent to afford multifunctional organoboron compounds is presented. Reactions of a wide range of 1,3-dienes with different substitution patterns promoted by an easily accessible phosphine-Cu complex proceed with high yields and regioselectivity.
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