期刊
NEW JOURNAL OF CHEMISTRY
卷 41, 期 24, 页码 15244-15250出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj03170j
关键词
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资金
- University grants commission (UGC-MRP) [41-309/2012]
- Department of Science and Technology (DST-SERB), New Delhi, India [SR/FT/CS-015/2009]
This study describes an ultrasensitive and highly selective dopamine (DA) assay that makes use of glutathione protected silver nanoclusters (GSH-AgNCs) acting as a nanoprobe. The GSH-AgNCs exhibit red fluorescence (with excitation/emission peaks at 490/645 nm), which increases on addition of DA, probably due to the hydrogen bonding interaction of the carboxyl groups of GSH-AgNCs and the amino groups of DA. The response is linear in the 20 x 10(-9) mol dm(-3) to 220 x 10(-9) mol dm(-3) DA concentration range, and the lowest limit of detection is 0.35 x 10(-9) mol dm(-3) (at an S/N ratio of 3). Potential interferents including uric acid, ascorbic acid, common metal ions, anions and some biologically relevant chemicals do not have an effect even in 100-fold higher concentrations. Furthermore, the present analytical assay was effectively utilized for the quantification of DA in spiked human urine samples.
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