期刊
NEW JOURNAL OF CHEMISTRY
卷 41, 期 16, 页码 8561-8567出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj00443e
关键词
-
资金
- Deutsche Forschungsgemeinschaft [DFG SP 392/45-1]
Solvatochromic measurements and H-1 NMR spectroscopy have been used to investigate the overall polarity of tetraalkylammonium (R3N+-CH3 with R = n-C4H9; n-C8H17) based ionic liquids (IL) and low temperature molten salts (LTMS), respectively, as function of the counter anion. Solvent acidity (SA), solvent basicity (SB), polarizability (SP) and dipolarity (SdP) parameters have been determined according to the Catalan scale. [Fe-II(1,10-phenanthroline)(2)(CN)(2)] (Fe), 3-(4-amino-3-methylphenyl)-7-phenylbenzol[1,2b:4,5-b']difuran-2,6-dione (ABF), 3-(4-N,N-dimethylaminophenyl)-7-phenylbenzol[1,2-b:4,5-b']-difuran-2,6-dione (DMe-ABF), 4-tert-butyl-2-(dicyanomethylene)-5-[4-(dimethylamino)benzylidene]-Delta(3)-thiazoline (Th), and 2-[4-(N,N-dimethylamino)benzylidene]malononitrile (BMN) have been used as solvatochromic polarity indicators. Significant correlations of the SB parameter of anion X- as a function of the chemical shift of the H-atoms of R3N+-CH3X- are presented and discussed. Thus, IL solvent basicity (SB) of the anion determines the interaction strength towards those CH-bonds in the direct vicinity of the ammonium nitrogen atom.
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