期刊
NEW JOURNAL OF CHEMISTRY
卷 41, 期 8, 页码 3089-3096出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03802f
关键词
-
资金
- Jilin Provincial Science and Technology Development Project of China [20150204001GX]
- 2015Y045
An effective method was proposed to prepare low dielectric constant composites based on a hybrid of graphene oxide-POSS and fluoropoly(ether ether ketone) (FPEEK). Through the formation of amide between aminopropylisobutyl polyhedral oligomeric silsesquioxane (POSS-NH2) and oxygen-containing groups (carboxyl groups) on graphene oxide (GO), the covalent functionalization of GO with POSS-NH2 (POSS-NH2-GO) hybrid was carried out, which is highly soluble in many organic solvents. The structure of the POSS-NH2-GO hybrid was confirmed by FT-IR, Raman, XRD, TGA, XPS, and TEM. The POSS-NH2-GO hybrid was well dispersed within the FPEEK polymer matrix to prepare POSS-NH2-GO/FPEEK composite films by solution blending. The dielectric constants of the composites decreased with the increasing content of POSS-NH2-GO hybrid, and a kappa value of 2.01 was achieved with the incorporation of the hybrid, only 3.0 wt% could cause a 92.8% high enhancement in Young's modulus.
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