期刊
ARKIVOC
卷 -, 期 -, 页码 154-171出版社
ARKAT USA INC
DOI: 10.24820/ark.5550190.p010.682
关键词
Intramolecular oxidation-reduction; 5-nitrosopyrimidines; 5-hydroxypteridine-6,7-diones
5-Nitrosopyrimidines are important scaffolds due to their unique structural and chemical properties, notable biological activities, and utilization in the syntheses of condensed heterocycles. A series of new 4-alkylamino-6-arylamino-5-nitrosopyrimidines are synthesized by intramolecular oxidation-reduction reactions of the corresponding ethyl-N-alkyl-N-(6-arylamino-5-nitropyrimidin-4-yl)glycinates. The title compounds exist as mixtures of two rotamers in CDCl3 solutions. [GRAPHICS] .
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