期刊
ELEMENTS
卷 11, 期 6, 页码 409-414出版社
MINERALOGICAL SOC AMER
DOI: 10.2113/gselements.11.6.409
关键词
reactive intermediates; biogeochemistry; manganese; sulfur; superoxide; hydrogen peroxide; disproportionation
资金
- NSF [EAR-1245919, EAR-1322790, OCE-1154307, OCE 1129553, CHE-1410688]
- NASA Astrobiology Institute [NNA15BB03A]
- Max Planck Society
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1410688] Funding Source: National Science Foundation
- Directorate For Geosciences
- Division Of Ocean Sciences [1129553, 1154307] Funding Source: National Science Foundation
The biogeochemical cycling of major and minor elements in the ocean has direct bearing on the health of the planet and its inhabitants. Reactive intermediates, of both chemical and biological origin, are emerging as important players in these biogeochemical cycles. Due to their rapid production and consumption, these reactive intermediates are short-lived and typically in low concentration. Involvement of these invisible species in biogeochemistry may therefore be hidden, or cryptic, with no obvious lingering chemical signature. Here, we highlight reactive intermediates of the oxygen, manganese, and sulfur cycles and how these intermediates are involved in cryptic cross-linkages between marine biogeochemical cycles of global importance.
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