期刊
ACS APPLIED ENERGY MATERIALS
卷 1, 期 9, 页码 4572-4579出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.8b00722
关键词
conjugated polyindole; porous carbons; hydrophilicity; supercapacitors; high energy density
资金
- National Natural Science Foundation of China [51662012, 51762018, 51572117]
- Outstanding Young Talent Project [20171BCB23076]
- Natural Science Foundation [20161BAB206147, 20171BAB206013]
- 5511 Project [20165BCB18016]
- Education Department Projects of Jiangxi Province [GJJ160762]
- School Level Youth Top-notch Project [2016QNBJRC001]
- Jiangxi Provincial Department of Education Innovation Fund of Postgraduates [YC2017-S410]
Three-dimensional carbon materials containing oxygen/nitrogen functional groups are facilely prepared by the carbonization of conjugated polyindole hollow nanospheres with the activation of 15 M KOH at 900 degrees C. The pore structures, surface elemental composition, and hydrophilicity of samples are studied by nitrogen adsorption-desorption isotherms, X-ray photoelectron spectroscopy, X-ray diffraction, transmission electron microscopy, energy-dispersive X-ray spectroscopy, scanning electron microscopy, Raman, and contact angle, respectively. The specific surface area of as-prepared carbon material with the micro/mesopore size distribution of 0.5-4 nm and macropores more than 100 nm is 2238 m(2) g(-1). The capacitance characterizations demonstrate that the specific capacitance of as-prepared carbon can reach 328 F g(-1). The device built from such carbon materials exhibits high energy density of about 15 Wh/kg, and 91% retention of original capacity after 10000 cycles. These positive data suggest that as-prepared three-dimensional materials will have a certain potential in the application of the electrochemical energy storage field.
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