期刊
ACS APPLIED ENERGY MATERIALS
卷 1, 期 9, 页码 4991-4997出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.8b00972
关键词
CsPbIBr2; precursor solution aging; low temperature; one-step method; all-inorganic solar cell
资金
- National Natural Science Foundation of China [61334002, 61106063]
- National Natural Science Foundation of Shaanxi Province [2018ZDCXL-GY-08-02-02]
- Fundamental Research Funds for the Central Universities [JB181107]
- Innovation Fund of Xidian University
Inorganic halide perovskite CsPbIBr2 with superior stability is regarded as a promising candidate for photovoltaic cells. However, a high-temperature annealing recipe (similar to 300 degrees C) is generally required to fulfill the crystallization of pure-phase CsPbIBr2 films. Herein, we report that precursor solution aging time strikingly affects the crystallization kinetics of CsPbIBr2 film in a one-step spin-coating method. Upon control of this subtle factor, crystallization temperature of pure-phase and full-coverage CsPbIBr2 films can be greatly lowered to 100 degrees C. Carbon-based all-inorganic planar cells with these CsPbIBr2 films yield a record efficiency of 6.55%, coupled with excellent long-term operational stability against moisture and heat. Our work for the first time suggests that CsPbIBr2 precursor aging time should be carefully concerned in a one-step solution method, and suggests a facile strategy to realize efficient and stable all-inorganic perovskite solar cells.
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