4.8 Article

Enhancement of photoelectrochemical oxidation by an amorphous nickel boride catalyst on porous BiVO4

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NANOSCALE
卷 9, 期 42, 页码 16133-16137

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr06636h

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资金

  1. National Key R&D Program of China [2016YFB0600901]
  2. National Science Foundation of China [21525626, U1463205, U1662111]
  3. Program of Introducing Talents of Discipline to Universities [B06006]

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This paper describes an amorphous nickel boride (NiB) electrocatalyst loaded on porous bismuth vanadate (BiVO4) with high activity for oxygen evolution in photoelectrochemical water oxidation. The NiB-decorated BiVO4 photoanode exhibits an onset potential of 0.25 V versus the reversible hydrogen electrode (vs. RHE) and a photocurrent of 3.47 mA cm(-2) at 1.23 V vs. RHE under simulated 100 mW cm(-2) irradiation.

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