期刊
NANOSCALE
卷 9, 期 27, 页码 9411-9420出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr01644a
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- Department of Science and Technology (DST) [DST-1272]
Herein, a novel heterostructure was fabricated by combining electrochemically and optically active materials to achieve a high capacitive response of 896 F g(-1) at 5 A g(-1). A network of ZnCo2O4 nanorods (NRs) was directly grown on a three-dimensional matrix of H : ZnO NRs (ZnCo2O4/H : ZnO NRs) that offered synergistic advantages by providing an optimum ion/charge transportation path, large electrochemically active surface area, and stable capacitive response during the electrolytic process. Furthermore, the fabricated solid-state asymmetric supercapacitor ZnCo2O4/H : ZnO NRs//activated carbon induced a large potential window of 1.5 V that offered excellent energy and power densities. In addition, optically active ZnCo2O4/H : ZnO NRs were also used for the conversion of optical energy over a broad wavelength range; thus, the as-fabricated asymmetric solid-state supercapacitor could easily provide the required power for the operation of a photodetector. Therefore, the unique heterostructure of ZnCo2O4/H : ZnO NRs not only presents excellent capacitive response but also demonstrates great potential for energy conversion.
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