期刊
NANOSCALE
卷 9, 期 35, 页码 13257-13263出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr04349j
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资金
- National Natural Science Foundation of China [51602113, 51372186]
- China Postdoctoral Science Foundation [2016 M590692]
Developing non-platinum catalysts for the oxygen reduction reaction (ORR) has become urgent for electrochemical energy devices. Herein, we synthesize N-doped hollow carbon nanospheres (N-HCNs) which only contain active pyridinic-N and graphitic-N by using polystyrene spheres and aniline as the corresponding template and precursor. The electrochemical measurements show that N-HCNs possess superior ORR electrocatalytic activity (half-wave potential is 15 mV higher than that of the precious Pt/C electrocatalyst), durability and anti-toxicity to Pt/C in alkaline media. Simultaneously, N-HCNs also reveal comparable ORR activity and superior stability to Pt/C in acidic media. Such high ORR performance can be ascribed to their hierarchical porous structure, ultra-high specific surface area, plenty of edge defects and high contents of active N atoms. It is noteworthy that when used as the catalyst for the air electrode of zinc-air batteries, N-HCNs present a higher power density and a larger operating voltage than Pt/C at the same discharge current density.
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