The ideal porous structure of EDLC carbon electrodes with extremely high capacitance

We propose an ideal porous structure of carbon electrodes for electric double-layer capacitors (EDLCs). The porous carbon successfully improved the gravimetric capacitance above similar to 200 F g(-1) even in an organic electrolyte by utilizing the carbon nanopore surface more effectively. High-resolution transmission electron microscopy images and X-ray diffraction patterns classified 15 different porous carbon electrodes into slit-shape and worm-like-shape, and the pore size distributions of the carbons were carefully determined applying the grand canonical Monte Carlo method to N-2 adsorption isotherms at 77 K. The ratio of pores where solvated ions and/ or desolvated ions can penetrate also has a significant effect on the EDL capacitance as well as the pore shape. The detailed study on the effect of porous morphologies on the EDLC performance indicates that a hierarchical porous structure with a worm-like shaped surface and a pore size ranging from a solvated ion to a solvent molecule is an ideal electrode structure.