期刊
NANO RESEARCH
卷 11, 期 7, 页码 3702-3709出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-017-1938-z
关键词
lithium-ion batteries; anode materials; germanium oxide; iron oxide; nanowires
类别
资金
- National Natural Science Foundation of China [21171015, 21373195, 51522212, 51421002]
- Recruitment Program of Global Experts
- program for New Century Excellent Talents in University [NCET-12-0515]
- Fundamental Research Funds for the Central Universities [WK340000004]
- Collaborative Innovation Center of Suzhou Nano Science and Technology
Germanium-based oxide has been found to be a promising high-capacity anode material for lithium-ion batteries (LIBs). However, it exhibits poor electrochemical performance because of the drastic volume change during cycling. Herein, we designed porous Ge-Fe bimetal oxide nanowires (Ge-Fe-O-x-700 NWs) by a large-scale and facile solvothermal reaction. When used as the anode material for LIBs, these Ge-Fe-O-x-700 NWs exhibited superior electrochemical performance (similar to 1,120 mAh.g(-1) at a current density of 100 mA.g(-1)) and good cycling performance (similar to 750 mAh.g(-1) after 50 cycles at a current density of 100 mA.g(-1)). The improved performance is due to the small NW diameter, which allows for better accommodation of the drastic volume changes and zero-dimensional nanoparticles, which shorten the diffusion length of ions and electrons.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据