期刊
NANO LETTERS
卷 17, 期 5, 页码 3068-3075出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.7b00421
关键词
Nanocrystal; quantum dot; magnetic polaron; diluted magnetic semiconductor; photoluminescence
类别
资金
- Office of Chemical Sciences, Biosciences, and Geosciences of the DOE Office of Basic Energy Sciences
- Los Alamos LDRD program
- Deutsche Forschungsgemeinschaft [ICRC TRR 160]
- NSF [DMR-1157490]
In semiconductors, quantum confinement can greatly enhance the interaction between band carriers (electrons and holes) and dopant atoms. One manifestation of this enhancement is the increased stability of exciton magnetic polarons in magnetically doped nanostructures. In the limit of very strong 0D confinement that is realized in colloidal semiconductor nanocrystals, a single exciton can exert an effective exchange field Bex on the embedded magnetic dopants that exceeds several tesla. Here we use the very sensitive method of resonant photoluminescence (PL) to directly measure the presence and properties of exciton magnetic polarons in colloidal Cd1-xMnxSe nanocrystals. Despite small Mn2+ concentrations (x = 0.4-1.6%), large polaron binding energies up to similar to 26 meV are observed at low temperatures via the substantial Stokes shift between the pump laser and the resonant PL maximum, indicating nearly complete alignment of all Mn2+ spins by Bex. Temperature and magnetic field-dependent studies reveal that B-ex approximate to 10 T in these nanocrystals, in good agreement with theoretical estimates. Further, the emission line widths provide direct insight into the statistical fluctuations of the Mn2+ spins. These resonant PL studies provide detailed insight into collective magnetic phenomena, especially in lightly doped nanocrystals where conventional techniques such as nonresonant PL or time-resolved PL provide ambiguous results.
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