期刊
ELECTROCHIMICA ACTA
卷 178, 期 -, 页码 407-413出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.08.015
关键词
Nitrogen functional graphene quantum dots; CdTe/CdS quantum dots; Anodic electrochemiluminescence; Ascorbic acid; Fruits
资金
- National Natural Science Foundation of China [21222507, 21305037, 21475037, 21235002]
- National Basic Research Program of China (973 Program) [2011CB911002]
- Foundation for Innovative Research Groups of NSFC [21221003]
- Excellent Youth Foundation of Hunan Scientific Committee [2015JJ1005]
- Fundamental Research Funds for the Central Universities
Herein, a CdTe/CdS QDs (with a CdTe core and a CdS shell) amplified electrogenerated chemiluminescence (ECL) of nitrogen functional graphene quantum dots (NGQDs) platform is reported. The utilization of CdTe/CdS QDs could facilitate the production of NGQDs radical, and then, a high yield of NGQDs* was formed due to the interaction of NGQDs radical with O-2(center dot), leading to an similar to 21-fold ECL enhancement. This ECL enhancing system does not require the addition of coreactant and modification of electrode which is carried out in homogeneous solution. Benefiting from the remarkable ECL enhancement effect, a feasible and sensitive ECL sensor was constructed for ascorbic acid (AA) quantification. The proposed method features a detection limit of 70 nM with a linear calibration range from 100 nM to 100 mu M, and exhibits good stability, practicability, and acceptable fabrication reproducibility, showing promising application in real-sample. (C) 2015 Elsevier Ltd. All rights reserved.
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