期刊
ELECTROCHIMICA ACTA
卷 174, 期 -, 页码 970-977出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.06.039
关键词
Sodium-ion battery; N-doped hollow carbon nanotubes; Binder effect; Sodium polyacrylate; Poly(vinylidene difluoride)
资金
- National Science Foundation of China [21175050]
- PCSIRT (Program for Changjiang Scholars and Innovation Research Team in University)
N-doped hollow carbon nanotubes (N-CNTs) with turbostratic structure are prepared as anode materials for sodium-ion battery. The effects of sodium polyacrylate (Na-PAA) and poly(vinylidene difluoride) (PVDF) binders on electrochemical performance are comparatively investigated. The obtained N-CNTs have disordered carbon structure and contain N-, O-functional groups, which electrochemical performance strongly depends on the binder used. The N-CNTs electrode with Na-PAA binder exhibits large capacity, high initial coulombic efficiency, excellent cycling stability and rate performance. Compared with the traditional PVDF binder, the water soluble Na-PAA binder shows electrochemical activity, lower internal resistance, and homogeneously formed solid electrolyte interface. Further investigations show that the binding capability of Na-PAA is closely related to the molecular weight. The Na-PAA with moderate molecular weight is more suitable as the binder of sodium-ion batteries with N-CNTs anode. (C) 2015 Elsevier Ltd. All rights reserved.
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