Nitrogen-modified carbon nanostructures derived from metal-organic frameworks as high performance anodes for Li-ion batteries

Here, we report preparation of nitrogen-modified nanostructure carbons through carbonization of Cu-based metal organic nanofibers at 700 degrees C under argon gas atmosphere. After removal of copper through chemical treatment with acids, pure N-modified nanostructure carbon with a nitrogen content of 8.62 wt % is obtained. When use as anodes for lithium-ion battery, the nanostructure carbon electrode has a discharge capacity of 853.1 mAh g(-1) measured at a current of 500 mA g(-1) after 800 cycles. (C) 2015 Elsevier Ltd. All rights reserved.