期刊
MOLECULES
卷 22, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/molecules22010144
关键词
mechanochemistry; coordination polymers; metal-organic frameworks; green chemistry; solid-state chemistry; solvent-free synthesis; reaction mechanisms; sustainable synthesis
资金
- FRQNT Doctoral Scholarship
- McGill University William J. Dawson Scholarship
- NSERC Discovery Grant program
Controlling the formation of coordination bonds is pivotal to the development of a plethora of functional metal-organic materials, ranging from coordination polymers, metal-organic frameworks (MOFs) to metallodrugs. The interest in and commercialization of such materials has created a need for more efficient, environmentally-friendly routes for making coordination bonds. Solid-state coordination chemistry is a versatile greener alternative to conventional synthesis, offering quantitative yields, enhanced stoichiometric and topological selectivity, access to a wider range of precursors, as well as to molecules and materials not readily accessible in solution or solvothermally. With a focus on mechanochemical, thermochemical and accelerated aging approaches to coordination polymers, including pharmaceutically-relevant materials and microporous MOFs, this review highlights the recent advances in solid-state coordination chemistry and techniques for understanding the underlying reaction mechanisms.
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