期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 1, 页码 87-90出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08985j
关键词
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资金
- National Natural Science Foundation of China [21625205, 21332003]
- National Program for Support of Top-Notch Young Professionals
The desymmetrization of p-quinols through a chiral bisguanidinium hemisalt catalyzed enantioselective Michael addition/lactonization cascade reaction with azlactones was reported. 3-Amino-benzofuran-2,5-diones containing a chiral amino acid residue were achieved with up to 99% ee and >19:1 dr. An exploration of the structure of the catalyst bisguanidinium was undertaken, revealing a bifunctional catalytic model.
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