4.7 Article

A chiral open-framework fluorinated cobalt phosphate consists of distorted F-encapsulated double 4-ring units with bulk homochirality

期刊

CHEMICAL COMMUNICATIONS
卷 55, 期 2, 页码 226-228

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07161f

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资金

  1. National Natural Science Foundation of China [21501196]
  2. Tianjin Research Program of Application Foundation and Advanced Technology [16JCQNJC03400, 15JCYBJC48700]
  3. Open Research Fund of Key Laboratory of Inorganic Synthesis and Preparative Chemistry [2015-26]
  4. Fundamental Research Funds for the Central Universities [3122013C014]
  5. Scientific Research foundation of Civil Aviation University of China [2013QD15X]
  6. Innovation and Entrepreneurship Fund for Undergraduates

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A homochiral open-framework fluorinated cobalt phosphate with a 2-fold interpenetrating diamond topology was ionothermally synthesized. The significant enantiomeric excess of the bulk product was confirmed by strong signals in its solid state circular dichroism (CD) spectrum.

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