期刊
ACS APPLIED BIO MATERIALS
卷 2, 期 1, 页码 480-487出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsabm.8b00674
关键词
organo-hydrogel; nanocellulose; Pickering emulsions; freezing tolerance
资金
- Fundamental Research Funds for the Central Universities [2662018PY060]
The increased quantities of fat in plants could allow the cells to inhibit the growth of ice and thus prevent the damages of their tissue structure in winter. In view of the structural buildup of freezing tolerance mechanism, here we presented a facile way of employing O/W Pickering emulsion as a template to produce the freestanding organo-hydrogels with increased mechanical stability and energy storage capacity. The oil droplets stabilized by cellulose nanofibrils were dispersed in the alginate polymer network that crosslinked with Ca2+, which resulted in homogeneous and closely packed microstructures. The prepared organo-hydrogels could maintain original gel structure under frozen conditions and had extraordinary mechanical performance. It could endure compressive stress up to 35 KPa (at 50% strain) and the elastic modulus was around 72 KPa, while the solid content of polysaccharides was only about 0.75%. By using our comprehensive strategy, organo-hydrogels with higher volumes of oil phase exhibited an enhanced cold storage capacity. For alginate hydrogel, it took 8 min when the temperature rose from 0 to 5 degrees C, while for the organo-hydrogel with oil volume of 30%, it took about 24 min. After 34 min, the inner temperature of alginate hydrogel was close to 25 degrees C, and about 70 min were needed for the temperature of organo-hydrogel to reach 25 degrees C. This kind of gel materials with complementary heteronetworks not only will have potential applications in cold chain logistics, but also can be applied in other fields with unusual functions.
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