4.7 Article

Manganese catalyzed α-methylation of ketones with methanol as a C1 source

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CHEMICAL COMMUNICATIONS
卷 55, 期 3, 页码 314-317

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08064j

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  1. Centre National de la Recherche Scientifique (CNRS)
  2. Universite Paul Sabatier
  3. Institut Universitaire de France (IUF)
  4. Agence Nationale de la Recherche (ANR Agency) [JCJC ANR-15-CE07-0001]

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The direct alpha-methylation of ketones with methanol under hydrogen borrowing conditions using a well-defined manganese (PNP)-P-3 complex as a pre-catalyst was, for the first time, achieved. The reactions typically proceed at 120 degrees C for 20 h with 3 mol% pre-catalyst loading and in the presence of NaOtBu (50 mol%) as base. The scope of the reaction was extended to the alpha-methylation of esters.

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