期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 7, 期 2, 页码 380-386出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8tc04495c
关键词
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资金
- Hong Kong Research Grants Council [HKBU 22304115-ECS, C5015-15GF]
- Areas of Excellence Scheme [AoE/P-03/08]
- Hong Kong Baptist University [FRG2/13-14/083]
- National Natural Science Foundation of China [51473139, 91333206, 20974091, 61631166001]
- Science, Technology and Innovation of Shenzhen [JCYJ20150630164505504]
- Innovation Platform Open Foundation of University of Hunan Province [14K092]
- Hunan 2011 Collaborative Innovation Center of Chemical Engineering & Technology with Environmental Benignity and Effective Resource Utilization
To address the intrinsic issue of conventional porphyrin derivatives with a deficient absorption between Soret and Q bands, we designed and synthesized two porphyrin molecules (BDTP-1 and BDTP-2) bearing a meso-alkyl substituted porphyrin core, benzodithiohene (BDT) ethynylene -bridge and end-capping ethylrhodanine derivatives. Apart from the characteristic Soret and Q bands of porphyrin macrocycle, an extra peak (521 nm for BDTP-1 and 536 nm for BDTP-2) was derived from the BDT units. Using the porphyrin small molecules as electron donors and PC71BM as an electron acceptor, the devices show broad spectral photocurrent generation with a significant contribution from greenlight-harvesting (490-550 nm), resulting in high performances with PCEs up to 7.97%.
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