期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 2, 页码 252-256出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob02826e
关键词
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资金
- National Natural Science Foundation of China [21602119, U1504208, 21702013]
- Beijing Natural Science Foundation [2184115]
- Fundamental Research Funds for the Central Universities [XK1802-6, buctrc201721]
The efficient synthesis of 2-substituted thiazoles and benzothiazoles has been accomplished employing readily available cysteine esters and 2-aminobenzenethiols as N and S sources. The reaction proceeds under an I-2/TBHP system and involves a one-pot tandem cyclization and oxidation sequence. A diverse range of aldehydes is amenable for this transition-metal-free protocol, which provides an alternative method to rapidly access thiazole-containing molecules.
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