期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 4, 页码 458-461出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc09229j
关键词
-
资金
- JSPS KAKENHI [18K14217]
- Grants-in-Aid for Scientific Research [18K14217] Funding Source: KAKEN
The electrophilic cyanation of allylic boranes, a process that is applicable to the construction of allylic quaternary carbon centers, is reported. The reaction has a broad substrate scope with a high functional group tolerance. The results represent an unprecedented and powerful tool for preparing synthetically useful ,-unsaturated nitriles, including derivatives that have been difficult to access using existing methods. The synthetic utility of the method was further demonstrated by functional group interconversions of the cyano group of the products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据