期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 166, 期 2, 页码 A89-A97出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.0221902jes
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资金
- National Science Foundation [1751590]
- Directorate For Engineering [1751590] Funding Source: National Science Foundation
- Div Of Civil, Mechanical, & Manufact Inn [1751590] Funding Source: National Science Foundation
The lack of a reliable rechargeable lithium metal (Li-metal) anode is a critical bottleneck for next-generation batteries. The unique mechanical properties of lithium influence the dynamic evolution of Li-metal anodes during cycling. While recentmodels have aimed at understanding the coupled electrochemical-mechanical behavior of Li-metal anodes, there is a lack of rigorous experimental data on the bulk mechanical properties of Li. This work provides comprehensive mechanical measurements of Li using a combination of digital-image correlation and tensile testing in inert gas environments. The deformation of Li was measured over a wide range of strain rates and temperatures, and it was fitted to a power-law creep model. Strain hardening was only observed at high strain rates and low temperatures, and creep was the dominant deformation mechanism over a wide range of battery-relevant conditions. To contextualize the role of creep on Li-metal anode behavior, examples are discussed for solid-state batteries, dead Li, and protective coatings on Li anodes. This work suggests new research directions and can be used to inform future electrochemical-mechanical models of Li-metal anodes. (C) The Author(s) 2019. Published by ECS.
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