期刊
ELECTROCHIMICA ACTA
卷 176, 期 -, 页码 130-140出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.07.004
关键词
aqueous batteries; composite electrode; DFT; intercalation kinetics; V2O5 xerogel
资金
- Ministry of Education, Science and Technological Development of Republic Serbia [III 45014]
- bilateral project Transition metal oxides as electrode materials for lithium ion batteries with Portuguese Foundation for Science and Technology
An amorphous V2O5 xerogel/graphite composite was synthesized and subjected to electrochemical characterization by cyclic voltammetry, chronopotentiometry and impedance measurements in aqueous LiNO3, NaNO3, KNO3 and Mg(NO3)(2) solutions. The kinetics of cyclic intercalation/deintercalation reactions, and the dependence of coulombic capacity on cycle number were examined. The capacity retention depended on the type of inserted ions and decreased in the following order: Mg2+ > Li+ > Na+ > K+. By ultraviolet/visible (UV/VIS) spectroscopy the concentration of dissolved vanadium oxide was determined and correlated with the capacity fade in various electrolyte solutions. By means of Density Functional Theory calculation (DFT), the bond strength between vanadium and triple coordinated oxygen in V2O5 was found to be responsible for the differences in its solubility in various aqueous solutions. (C) 2015 Elsevier Ltd. All rights reserved.
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