期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 51, 期 -, 页码 81-84出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2014.12.009
关键词
Pyrite; Thin film; Conversion reaction; Lithium microbattery; Solid-state battery
All-solid-state thin film batteries based on sputtered pyrite electrodes, a lithium phosphorus oxynitride electrolyte and a lithium anode were prepared and characterized. The successive reduction of both S-2(2-) and Fe2+ species led to an impressive volumetric discharge capacity, five times higher than the one for LiCoO2. Excellent reversibility and capacity retention were obtained during the first and the subsequent 800 charge-discharge cycles. A continuous cycling in the low voltage domain was found to be detrimental to the reversibility of the conversion reaction, suggesting a progressive evolution of the phase distribution inside the electrode. The initial capacity was easily recovered after few full oxidation cycles. (C) 2014 Elsevier B.V. All rights reserved.
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