4.4 Article

Mn(OAc)3-Mediated Regioselective C-H Phosphonylation of Indolizines with H-Phosphonates

期刊

CHEMISTRYSELECT
卷 4, 期 3, 页码 1117-1120

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201804056

关键词

Indolizines; H-Phosphonates; Phosphonylation; Mn(OAc)(3)-Mediated

资金

  1. Science and Technology Planning Project of Guangzhou [201806040009, 201804010349]
  2. Provincial Experimental Teaching Demonstration Center of Chemistry & Chemical Engineering
  3. Guangdong Cosmetics Engineering & Technology Research Center

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A range of indolizines and H-phosphonates smoothly underwent Mn(OAc)(3)-mediated C-H phosphonylation procedure to afford the phosphorylated indolizines in good to excellent yields with high regioselectivities. Mechanistic studies have been conducted to clarify the radical pathway.

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