期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 7, 页码 937-940出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc08768g
关键词
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资金
- Miami University
- NSF [DUE-1432466]
Oxidized products have become increasingly valuable as building blocks for a wide variety of different processes and fine chemistry, especially in the benzylic position. We report herein a sustainable protocol for this transformation through C-H functionalization and is performed using electrochemistry as the main power source and tert-butyl hydroperoxide as the radical source for the C-H abstraction. The temperature conditions reported here do not increase above 50 degrees C and use an aqueous-based medium. A broad substrate scope is explored, along with bioactive molecules, to give comparable and increased product yields when compared to prior reported literature without the use of electrochemistry.
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