期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 7, 页码 901-904出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07709f
关键词
-
资金
- Ministry of Education and Science of the Russian Federation [16.3871.2017/4.6]
We report a careful investigation of a selective phase formation in the zirconium-terephthalic acid system during solvothermal synthesis, which could result in the UiO-66 (Zr6O6(OH)(4)(BDC)(6)) or MIL-140A (ZrO(BDC)) metal-organic frameworks (MOFs). The introduction of water varies the phase from MIL-140A to UiO-66 by producing at the nucleation stage tetragonal ZrO2 nanoparticles, where the local arrangement of Zr and O atoms is similar to that in the UiO-66 SBU.
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